MTL - Peach and Plum Do Not Speak (The Silent Cherry And Plum Blossoms) - Chapter 44

When our protagonist becomes the game character Jun Karentia, she thinks she has it made. She may be just a lowly support mage, but with her knowledge of the game, she knows she can finagle her way to the good ending following around the main character, Fabian. The problem? This game doesn’t end after one playthrough. Jun is prepared to guide Fabian through the second playthrough to the true ending when… Fabian abandons her. Now the Grand Duke Mayer Knox—captain of the Dark Knights and the secret final boss—is determined to have her join his party. Can Jun turn the final boss into the main character? Why is Mayer Knox so intent on having her in his party? And when will these rumors about being his lover stop?!

I am Master Siwei, and I speak for arcane arts.
This is an era of heroes and heroines.
This is an era of great changes.
In the end, it will be an arcane era opened by me.

- Description from Novelupdates

A series of short stories in the world of Toaru Majutsu no Index organized into chapters featuring Kanzaki Kaori as the protagonist, going around the world and space doing missions for the Church of Necessary Evil, however, there is more than meets the eye as each incident is connected.

One chapter was bundled with each limited edition release of the Toaru Kagaku no Railgun anime DVD and BDs, with all of them together being equivalent to a single normal Toaru Majutsu no Index volume